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Volume 4, issue 1 | Copyright
SOIL, 4, 63-81, 2018
https://doi.org/10.5194/soil-4-63-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Original research article 15 Feb 2018

Original research article | 15 Feb 2018

Saturated and unsaturated salt transport in peat from a constructed fen

Reuven B. Simhayov1, Tobias K. D. Weber1,2,a, and Jonathan S. Price1 Reuven B. Simhayov et al.
  • 1Department of Geography, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada
  • 2Soil Science and Soil Physics Division, Institute of Geoecology, TU Braunschweig, Langer Kamp 19c, 38106 Braunschweig, Germany
  • anow at: Institute for Soil Science and Land Evaluation, Biogeophysics, University of Hohenheim, Emil-Wolff-Straße 27, 70599 Stuttgart, Germany

Abstract. The underlying processes governing solute transport in peat from an experimentally constructed fen peatland were analyzed by performing saturated and unsaturated solute breakthrough experiments using Na+ and Cl as reactive and non-reactive solutes, respectively. We tested the performance of three solute transport models, including the classical equilibrium convection–dispersion equation (CDE), a chemical non-equilibrium one-site adsorption model (OSA) and a model to account for physical non-equilibrium, the mobile–immobile (MIM) phases. The selection was motivated by the fact that the applicability of the MIM in peat soils finds a wide consensus. However, results from inverse modeling and a robust statistical evaluation of this peat provide evidence that the measured breakthrough of the conservative tracer, Cl, could be simulated well using the CDE. Furthermore, the very high Damköhler number (which approaches infinity) suggests instantaneous equilibration between the mobile and immobile phases underscoring the redundancy of the MIM approach for this particular peat. Scanning electron microscope images of the peat show the typical multi-pore size distribution structures have been homogenized sufficiently by decomposition, such that physical non-equilibrium solute transport no longer governs the transport process. This result is corroborated by the fact the soil hydraulic properties were adequately described using a unimodal van Genuchten–Mualem model between saturation and a pressure head of ∼ −1000cm of water. Hence, MIM was not the most suitable choice, and the long tailing of the Na+ breakthrough curve was caused by chemical non-equilibrium. Successful description was possible using the OSA model. To test our results for the unsaturated case, we conducted an unsaturated steady-state evaporation experiment to drive Na+ and Cl transport. Using the parameterized transport models from the saturated experiments, we could numerically simulate the unsaturated transport using Hydrus-1-D. The simulation showed a good prediction of observed values, confirming the suitability of the parameters for use in a slightly unsaturated transport simulation. The findings improve the understanding of solute redistribution in the constructed fen and imply that MIM should not be automatically assumed for solute transport in peat but rather should be evidence based.

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Lab experiments were performed to understand solute transport in peat from an experimental fen. Transport was analyzed under saturated and unsaturated conditions using NaCl (salt). We tested the applicability of a physical-based model which finds a wide consensus vs. alternative models. Evidence indicated that Cl transport can be explained using a simple transport model. Hence, use of the physical transport mechanism in peat should be evidence based and not automatically assumed.
Lab experiments were performed to understand solute transport in peat from an experimental fen....
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